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Catalytic transformations of cyclohexadienes in presence of Ru-C

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Ru-C catalyzes the disproportionation of the cyclohexadienes to cyclohexene and benzene (inert atmosphere, 80°C). In the presence of hydrogen (20°C) the ratioof the 1, 3-cyclohexadiene disproportionation/hydrogenation rates is 4–20 times smaller than on other group VIII metals.

  2. 2.

    On Ru-C the relative adsorbability, and the rate and selectivity of hydrogenation, are lower for 1,4-cyclohexadiene than for 1,3-cyclohexadiene.

  3. 3.

    1, 4-Cyclohexadiene experiences unusually strong adsorption displacement by the reaction product, namely benzene, which deactivates the catalyst.

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Literature cited

  1. P. N. Rylander, Catalytic Hydrogenation over Platinum Metals, Academic Press, New York-London (1967).

    Google Scholar 

  2. L. Kh. Freidlin, E. F. Litvin, and S. K. Tillyaev, Neftekhimiya,8, 155 (1968).

    Google Scholar 

  3. L. Kh. Freidlin, B. D. Polkovnikov, and Yu. P. Egorov, Izv. Akad. Nauk SSSR, Ser. Khim., 910 (1959).

  4. L. Kh. Freidlin, I. L. Popova, and T. P. Dadze, Izv. Akad. Nauk SSSR, Ser. Khim., 2204 (1972).

  5. L. Kh. Freidlin and I. L. Popova, Izv. Akad. Nauk SSSR, Ser. Khim., 1514 (1968).

  6. J. E. Lyons, J. Catalysis,28, 500 (1973).

    Google Scholar 

  7. R. B. Bates, R. H. Carnigham, and C. E. Staples, J. Am. Chem. Soc.,85, 3030 (1963).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    L. Kh. Freidlin & I. L. Popova

Authors
  1. L. Kh. Freidlin
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  2. I. L. Popova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1109–1111, May, 1975.

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Freidlin, L.K., Popova, I.L. Catalytic transformations of cyclohexadienes in presence of Ru-C. Russ Chem Bull 24, 1016–1018 (1975). https://doi.org/10.1007/BF00922955

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  • DOI: https://doi.org/10.1007/BF00922955

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