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Photopolymerization of styrene in the presence of titanium compounds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The photopolymerization of styrene in the presence of titanium compounds Cp2TiC2H5Cl, Cp2TiCl (CPh3), Cp2TiCl2, TiCl4, Ti(CH2C6H5)4 under the action of visible light was studied.

  2. 2.

    The decomposition of the Ti-C bond under the action of quanta of visible light occurs during complex formation of the monomer with organometallic derivatives of titanium.

  3. 3.

    In the case of photoinitiators with a titanium-carbon bond, the polymerization of styrene under the action of visible light occurs according to a radical mechanism.

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Authors and Affiliations

  1. Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    T. S. Dzhabiev, F. S. D'yachkovskii & L. I. Chernaya

Authors
  1. T. S. Dzhabiev
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  2. F. S. D'yachkovskii
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  3. L. I. Chernaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1091–1095, May, 1975.

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Dzhabiev, T.S., D'yachkovskii, F.S. & Chernaya, L.I. Photopolymerization of styrene in the presence of titanium compounds. Russ Chem Bull 24, 1000–1003 (1975). https://doi.org/10.1007/BF00922952

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  • DOI: https://doi.org/10.1007/BF00922952

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