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Catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymerization under the action of carbon monoxide and hydrogen

Communication 49. The influence of additions of oxides and salts of alkali and alkaline earth metals on the activity of Co-aluminum hydroxide and Co-clay catalysts in the hydropolymerization of ethylene

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Additions of ions of the alkali and alkaline earth metals, beryllium, and magnesium have little effect on the activity of a Co-aluminum hydroxide catalyst in the hydropolymerization of ethylene, initiated by carbon monoxide.

  2. 2.

    A Co-clay catalyst in the same reaction is promoted by small additions (oxide up to 5% of the weight of Co) of the lithium ion, is deactivated by additions of sodium, potassium, and cesium ions (5% or more), and shows little change in activity under the influence of additions of ions of beryllium, magnesium, the alkaline earth metals, and large quantities (10%) of lithium.

  3. 3.

    Sulfates, phosphates, and chlorides act as poisons on both types of catalysts.

  4. 4.

    Neutralization of the acid centers of the carriers of the catalysts considered does not influence their activity.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    I. V. Guseva & Ya. T. Éidus

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  1. I. V. Guseva
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  2. Ya. T. Éidus
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.5, pp. 1059–1065, May, 1969.

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Guseva, I.V., Éidus, Y.T. Catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymerization under the action of carbon monoxide and hydrogen. Russ Chem Bull 18, 968–972 (1969). https://doi.org/10.1007/BF00922851

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  • DOI: https://doi.org/10.1007/BF00922851

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