Conclusions
-
1.
In the decomposition of vapors of nitroform, fluoro- and chlorodinitromethane under static conditions, a significant influence on the rate is exerted by a reaction proceeding on the surface of the reaction vessel. A consideration of this reaction permits a determination of the characteristics of homogeneous decomposition, which in the case of nitroform and fluorodinitromethane, agree with the radical mechanism of decomposition.
-
2.
The thesis that H and F atoms have the same effect on the energy of cleavage of the C-N bond in the nitro-compounds studied was confirmed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Dokl. Akad. Nauk SSSR,177, 1128 (1968).
G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Dokl. Akad. Nauk SSSR,177, 1387 (1968).
G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 383 (1968).
G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2629 (1968).
G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2628 (1968).
G. M. Nazin, G. B. Manelis, and F. I. Dubovitskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2631 (1968).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1035–1039, May, 1969.
The authors would like to thank L. T. Eremenko and A. A. Fainzil'berg for providing the substances for investigation.
Rights and permissions
About this article
Cite this article
Nazin, G.N., Manelis, G.B. & Dubovitskii, F.I. Thermal decomposition of nitroform and related compounds in the gas phase. Russ Chem Bull 18, 945–948 (1969). https://doi.org/10.1007/BF00922846
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00922846