Conclusions
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1.
The reaction of tetrakis(trifluoromethy1)allene with π-C5H5Fe(CO) −2 and Re(CO) −5 gives σ-complexes.
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2.
On irradiation and heating, the σ-complex of iron is converted into the π-allylidene complex.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, pp. 1124–1129, May, 1976.
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Nesmeyanov, A.N., Kolobova, N.E., Zlotina, I.B. et al. The reaction of tetrakis(trifluoromethyl)allene with sodium derivatives of iron and rhenium carbonyls. Russ Chem Bull 25, 1093–1097 (1976). https://doi.org/10.1007/BF00921999
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DOI: https://doi.org/10.1007/BF00921999