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Mass spectra of tetranitromethane and some of its alpha halide derivatives

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the pyrolysis of fluorodinitroazidomethane, for the very first time we have recorded the formation of ions corresponding in mass to fluoronitrocarbene and the fluoronitroazidomethane radical.

  2. 2.

    In the series of aliphatic polynitrocompounds we have also recorded the molecular trinitromethane ion for the first time.

  3. 3.

    We have obtained indirect data as to the formation of dinitrocarbene during the pyrolysis of trinitromethane.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1057–1061, May, 1976.

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Kolosov, V.D., Orlova, M.K., Osipov, G.A. et al. Mass spectra of tetranitromethane and some of its alpha halide derivatives. Russ Chem Bull 25, 1028–1032 (1976). https://doi.org/10.1007/BF00921985

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  • DOI: https://doi.org/10.1007/BF00921985

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