Conclusions
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1.
In the pyrolysis of fluorodinitroazidomethane, for the very first time we have recorded the formation of ions corresponding in mass to fluoronitrocarbene and the fluoronitroazidomethane radical.
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2.
In the series of aliphatic polynitrocompounds we have also recorded the molecular trinitromethane ion for the first time.
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3.
We have obtained indirect data as to the formation of dinitrocarbene during the pyrolysis of trinitromethane.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1057–1061, May, 1976.
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Kolosov, V.D., Orlova, M.K., Osipov, G.A. et al. Mass spectra of tetranitromethane and some of its alpha halide derivatives. Russ Chem Bull 25, 1028–1032 (1976). https://doi.org/10.1007/BF00921985
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DOI: https://doi.org/10.1007/BF00921985