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Interaction of the o-benzosemiquinone radical with the divalent copper ion

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The absorption spectrum was recorded, and the value of the rate constant of the disproportionation of the o-benzosemiquinone radical QH. was obtained in the interaction with the Cu2+. It was shown that pKQH.>7.

  2. 2.

    The formation of a complex between the radical QH. and the Cu2+ ions, with a 1∶1 composition, was demonstrated. The spectral kinetic characteristics of such a complex and the constant of complex formation were obtained.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. A. Kuz'min, I. V. Khudyakov, A. V. Popkov & L. L. Koroli

Authors
  1. V. A. Kuz'min
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  2. I. V. Khudyakov
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  3. A. V. Popkov
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  4. L. L. Koroli
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2431–2435, November, 1975.

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Kuz'min, V.A., Khudyakov, I.V., Popkov, A.V. et al. Interaction of the o-benzosemiquinone radical with the divalent copper ion. Russ Chem Bull 24, 2319–2322 (1975). https://doi.org/10.1007/BF00921640

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  • DOI: https://doi.org/10.1007/BF00921640

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