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Telomerization of propylene with ethyl formate

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Telomerization of propylene with ethyl formate is accompanied by a rearrangement of the radicals via a 1,6-migration of the H atom. The 1,4-migration of the H atom does not take place.

  2. 2.

    The first observed telomerization of propylene giving hydrocarbon type telomers was described.

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Literature cited

  1. A. B. Terent'ev, N. S. Ikonnikov, V. I. Dostovalova, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,213, 1345 (1973).

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  2. R. Kh. Friedlina, S. N. Aminov, and A. B. Terent'ev, Dokl. Akad. Nauk SSSR,156, 1133 (1964).

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  3. P. A. Zagorets, I. N. Bryantsev, and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 909 (1976).

  4. R. Kh. Friedlina, A. B. Terent'ev, and V. I. Dostovalova, Izv. Akad. Nauk SSR, Ser. Khim., 2125 (1972).

  5. N. S. Ikonnikov and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 371 (1975).

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Authors and Affiliations

  1. Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    M. A. Churilova, A. B. Terent'ev & R. Kh. Friedlina

Authors
  1. M. A. Churilova
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  2. A. B. Terent'ev
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  3. R. Kh. Friedlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 121–125, January, 1977.

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Churilova, M.A., Terent'ev, A.B. & Friedlina, R.K. Telomerization of propylene with ethyl formate. Russ Chem Bull 26, 103–106 (1977). https://doi.org/10.1007/BF00921503

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  • DOI: https://doi.org/10.1007/BF00921503

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