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Kerr constants and spatial structures of certain aryl vinyl compounds of sulfur

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The aryl group is rotated by an angle of 65–75° with respect to the C-S-C plane in the aryl vinyl sulfones and theirβ-chloroderivatives containing H, CH3, CL, and Br substituents; in nitrophenyl vinyl sulfone, the rotation is 4–28°.

  2. 2.

    The unsaturated group inthe aryl vinyl sulfones, aryl trans-β-chlorovinyl sulfones, and the aryl trans-β-chlorovinyl sulfides have s-trans conformation, or something close thereto, displacement out of the C-S-C plane being as high as 40°.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch of the Academy of Sciences of the USSR, USSR

    T. G. Mannafov, S. G. Vul'fson, I. A. Arkhireeva & A. N. Vereshchagin

  2. V. I. Ul'yanov-Lenin Kazan State University, USSR

    T. G. Mannafov, S. G. Vul'fson, I. A. Arkhireeva & A. N. Vereshchagin

Authors
  1. T. G. Mannafov
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  2. S. G. Vul'fson
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  3. I. A. Arkhireeva
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  4. A. N. Vereshchagin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 101–105, January, 1977.

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Mannafov, T.G., Vul'fson, S.G., Arkhireeva, I.A. et al. Kerr constants and spatial structures of certain aryl vinyl compounds of sulfur. Russ Chem Bull 26, 86–90 (1977). https://doi.org/10.1007/BF00921499

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  • DOI: https://doi.org/10.1007/BF00921499

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