Conclusions
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1.
Study has been made of the kinetics of the ethylbenzene hydroperoxide breakdown in the presence of molybdenum rezinate, working in ethylbenzene solution at temperatures ranging from 60 to 120°C.
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2.
Catalytic breakdown of ethylbenzene hydroperoxide proceeds through the formation of a complex between the hydroperoxide and the catalyst; it is inhibited by the product water and methylphenylcarbonyl in their competition with the hydroperoxide for positions within the catalyst coordination sphere.
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3.
The uncatalyzed reaction is first order in the hydroperoxide, the rate being 2–3 orders less than that of the catalyzed process.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 29–33, January, 1977.
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Gavrilenko, V.A., Evzerikhin, E.I. & Moiseev, I.I. Kinetics and mechanism of olefin epoxidation by hydroperoxide in the presence of molybdenum compounds. Russ Chem Bull 26, 20–24 (1977). https://doi.org/10.1007/BF00921484
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DOI: https://doi.org/10.1007/BF00921484