Conclusions
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1.
Calculations of the atomization energies of Cr(CO)6, Fe(CO)5, Mo(CO)6, Ni(CO)4, MnH(CO)5, FeH2(CO)4, and CoH(CO)4 molecules have been carried out by the virial-statistical method.
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2.
The results of these calculations suggest that the stabilities decrease in the order MnH(CO)5 > FeH2(CO)4 > CoH (CO)4, a conclusion consistent with experimental data.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 16–19, January, 1977.
I would like to thank D. A. Bochvar for a discussion of these results.
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Borisov, Y.A. Virial-statistical method of calculating atomic and molecular energies. Russ Chem Bull 26, 8–11 (1977). https://doi.org/10.1007/BF00921481
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DOI: https://doi.org/10.1007/BF00921481