Summary
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1.
In the reactions of o-allylphenol and of o-allylphenoxytrimethylsilane with alkoxy alkyl hydrogen silanes o-allylphenoxytrimethylsilane adds at its double bond to silicon, whereas in the case of o-allylphenol the hydroxyl group also reacts.
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2.
The alcoholysis of the products of the reaction of o-allylphenoxytrimethylsilane with alkoxy alkyl hydrogen silanes does not lead to the formation of organosilicon compounds containing a hydroxyphenyl group. In this reaction cyclic compounds are formed, and by the hydrolysis of these, polysiloxanes containing hydroxyphenyl groups, may be obtained.
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3.
Fifteen previously undescribed compounds were isolated and characterized.
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Literature cited
J. L. Speier, R. Zimmerman, and J. Webster, J. Amer. Chem. Soc.78, 2278 (1956); British Pat. 769497(1957).
Organic Reactions, Collection 2 [Russian translation], IL, Moscow (1950), pp. 35–37.
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Andrianov, K.A., Pakhomov, V.I. & Lapteva, N.E. Reactions of o-allylphenol and of o-allylphenoxy-trimethylsilane with alkoxy alkyl hydrogen silanes. Russ Chem Bull 11, 1948–1954 (1962). https://doi.org/10.1007/BF00921353
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DOI: https://doi.org/10.1007/BF00921353