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Carbonylation reactions

24. Effect of some oxidizing agents as initiators for the carbonylation of amines with carbon monoxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was shown by the UV spectroscopy method that the active initiators of the Liquid-phase carbonylation of amines with CO are oxidizing agents that form charge-transfer complexes with the amines.

  2. 2.

    The carbonylation of piperidine with CO in the presence of I2 or KMnO4 is inhibited by excess initiator The addition of a second initiator to the reaction system retards the carbonylation due to a decrease in the rate of forming the complex of the first initiator with the amine.

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Literature cited

  1. B. K. Nefedov, V. A. Petukhov, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim., 2535 (1974).

  2. J. Tsuji, J. Synth. Org. Chem. Japan,25, 984 (1967).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. K. Nefedov, V. A. Petukhov, N. S. Sergeeva & Ya. T. Éidus

Authors
  1. B. K. Nefedov
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  2. V. A. Petukhov
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  3. N. S. Sergeeva
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  4. Ya. T. Éidus
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1541–1545, July, 1976.

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Nefedov, B.K., Petukhov, V.A., Sergeeva, N.S. et al. Carbonylation reactions. Russ Chem Bull 25, 1466–1469 (1976). https://doi.org/10.1007/BF00920820

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  • DOI: https://doi.org/10.1007/BF00920820

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