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Mass-spectrometric determination of the 4-center configuration in trans-linked 1,4-dialkyldecahydroquinolol-4′s

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

By studying molecular ion stabilities and values of the\(I_{[M - C_2 H_5 ]^ + } /I_{[M]^ + } \) ratio (the [M-C2H5]+ results from 4-C2H5 group elimination), we have been led to 4-center configurations for the trans-linked 1-alkyl-4-ethyl(ethynyl)decahydroquinolol-4′s (Alk=CH3, C2H5, n-and i-C3H7).

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Syntheses, Academy of Sciences of the USSR, Moscow

    V. G. Zaikin, V. I. Smetanin, N. S. Vul'fson, A. A. Akhrem, L. I. Ukhova & G. P. Kukso

  2. M. M. Shemyakin Institute of Bioorganic Chemistry, Academy of Sciences of the USSR, Moscow

    V. G. Zaikin, V. I. Smetanin, N. S. Vul'fson, A. A. Akhrem, L. I. Ukhova & G. P. Kukso

  3. Institute of Bioorganic Chemistry, Academy of Sciences of the Belorussian SSR, Minsk

    V. G. Zaikin, V. I. Smetanin, N. S. Vul'fson, A. A. Akhrem, L. I. Ukhova & G. P. Kukso

Authors
  1. V. G. Zaikin
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  2. V. I. Smetanin
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  3. N. S. Vul'fson
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  4. A. A. Akhrem
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  5. L. I. Ukhova
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  6. G. P. Kukso
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1524–1529, July, 1976.

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Zaikin, V.G., Smetanin, V.I., Vul'fson, N.S. et al. Mass-spectrometric determination of the 4-center configuration in trans-linked 1,4-dialkyldecahydroquinolol-4′s. Russ Chem Bull 25, 1452–1455 (1976). https://doi.org/10.1007/BF00920817

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  • DOI: https://doi.org/10.1007/BF00920817

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