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Oxidation of transition metals in the liquid phase

2. Direct synthesis of complexes of cobalt, nickel, and copper with acetonitrile, dimethylformamide, dimethyl sulfoxide, and dimethylacetamide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have oxidized Co, Ni, and Cu by organic halogen-containing compounds and by bromine under mild conditions.

  2. 2.

    By reacting the metals Co, Ni, and Cu with organic halogen-containing compounds (RX) and Br2 in polar aprotic solvents (L) we have obtained complexes with the general formula NX2Ln, where n≤6, in which the metal is in oxidation state +2.

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Authors and Affiliations

  1. Division of the Institute of Physical Chemistry, Academy of Sciences of the USSR, Chernogolovka

    S. N. Kurskov, I. N. Ivleva, I. P. Lavrent'ev, O. S. Filipenko & M. L. Khidekel'

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  1. S. N. Kurskov
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  2. I. N. Ivleva
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  3. I. P. Lavrent'ev
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  4. O. S. Filipenko
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  5. M. L. Khidekel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1442–1448, July, 1976.

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Kurskov, S.N., Ivleva, I.N., Lavrent'ev, I.P. et al. Oxidation of transition metals in the liquid phase. Russ Chem Bull 25, 1380–1385 (1976). https://doi.org/10.1007/BF00920799

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  • DOI: https://doi.org/10.1007/BF00920799

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