Skip to main content
Log in

Dipole moments and structure of derivatives of phenyl benzoate

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The dipole moments were determined for 18 para- and ortho-substituted phenyl benzoates in benzene and dioxane solutions. The benzene rings and phenyl benzoates have an S-trans-orientation.

  2. 2.

    In ortho-substituted phenyl benzoates, the molecule is not coplanar. In dioxane the conformation of the molecules changes in the direction of the more coplanar structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. V. V. Korshak, G. L. Slonimskii, S. V. Vinogradova, A. A. Askadskii, A. V. Vasil'ev, A. V. Vasnev, and K. A. Bychko, Dokl. Akad. Nauk SSSR,199, 607 (1971).

    Google Scholar 

  2. V. V. Korshak, S. A. Pavlova, L. V. Dubrovina, V. A. Vasnev, S. V. Vinogradova, and A. V. Vasil'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 1409 (1972).

  3. B. Eda and K. Ito, Bull. Chem. Soc. Japan,29, 524 (1956);30, 164 (1957).

    Google Scholar 

  4. V. I. Minkin, O. A. Osipov, and Yu. A. Zhdanov, Dipole Moments in Organic Chemistry [in Russian], Khimiya, Leningrad (1968).

    Google Scholar 

  5. V. J. Minkin, Yu. A. Zhdanov, E. A. Medyantzeva, and Yu. A. Ostroumov, Tetrahedron,23, 3651 (1967).

    Google Scholar 

  6. Ch. H. Rao, Electronic Spectra in Chemistry [Russian translation], Mir (1964).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 778–782, April, 1975.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kolodyazhnyi, Y.V., Vasnev, V.A., Lapin, I.A. et al. Dipole moments and structure of derivatives of phenyl benzoate. Russ Chem Bull 24, 701–704 (1975). https://doi.org/10.1007/BF00920677

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00920677

Keywords

Navigation