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The reaction of 6-nitro alcohols with ethoxyacetylene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Ethoxyacetylene was reacted with 2-nitroethanol, 2,2,2-trinitroethanol and 2,2-dinitropropanediol in the presence of hydrogen chloride and the corresponding acetates were obtained.

  2. 2.

    The theory was expressed that the chlorine atom in Β -nitrochloroalkanes in less labile than the chlorine atom in the corresponding unsubstituted aliphatic chloroparaffins.

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Literature cited

  1. A. E. Favorskii and M. N. Shchukina, Zhur. Obshchei Khim.15, 394 (1945).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    S. S. Novlkov, G. A. Shvekhgelmer & N. F. Pyatakov

Authors
  1. S. S. Novlkov
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  2. G. A. Shvekhgelmer
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  3. N. F. Pyatakov
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Novlkov, S.S., Shvekhgelmer, G.A. & Pyatakov, N.F. The reaction of 6-nitro alcohols with ethoxyacetylene. Russ Chem Bull 10, 351–352 (1961). https://doi.org/10.1007/BF00919585

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  • DOI: https://doi.org/10.1007/BF00919585

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