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Study of the stepwise dehydration of 1,6-hexanediol on tricalcium phosphate catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The dehydration of 1,6-hexanediol on tricalcium phosphate catalyst results in the simultaneous formation of both the partial (hexenol, hexamethylene oxide) and complete (hexadiene) dehydration products of the glycol. The latter (hexadiene) is obtained mainly through the intermediate formation of the hexenol, which is less stable than the oxide.

  2. 2.

    Isomerization of the formed oxide and migration of the double bonds in the diolefin accompany the main process.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    L. Kh. Freidlin, V. Z. Sharf & N. S. Andreev

Authors
  1. L. Kh. Freidlin
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  2. V. Z. Sharf
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  3. N. S. Andreev
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Additional information

The authors wish to thank V. V. An and B. L. Lebedev for performing the Chromatographie analyses.

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Freidlin, L.K., Sharf, V.Z. & Andreev, N.S. Study of the stepwise dehydration of 1,6-hexanediol on tricalcium phosphate catalyst. Russ Chem Bull 10, 348–350 (1961). https://doi.org/10.1007/BF00919584

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  • DOI: https://doi.org/10.1007/BF00919584

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