Summary
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1.
The products from the reaction of platinum with oxygen at moderate temperatures are various platinum peroxides.
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2.
Even on a pure platinum surface, oxygen is chemisorbed without decomposition of the molecules to atoms.
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3.
In the formation of a peroxide film there are considerable changes in the structure of the surface of the metal itself, which shows, in particular, in a change in the orientation of its crystals.
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Literature cited
W. J. Moore and L. Pauling, J. Amer. Chem. Soc.63, 1392 (1941).
E. E. Galloni and R. H. Busch, J. Chem. Phys20, 198 (1952).
S. M. Ariya, M. P. Morozova, G. S. Markevich, and A. A. Reikhardt, Collection of Articles on General Chemistry [in Russian]1, 76 (1953).
G. I. Finch, C. A. Murison, N. Stuart, and G. P. Thomson, Proc. Roy. Soc. (London)A141, 414 (1933).
A. Baroni, Atti Linc. (6),21, 756 (1935).
R. H. Busch, Z. Naturforschung5b, 130 (1950).
O. Goche, Bull. cl. sci. Acad, roy Belgique37, 393 (1951).
R. H. Busch, E. E. Galloni, J. Kaskovan, and A. E. Cairo, Anais. Acad. brasil cienc.24, 185 (1952).
N. A. Shishakov, Kristallografiya2, 689 (1957).
N. A. Shishakov, V. V. Andreeva, and N. K. Andrushchenko, Structure and Mechanism of the Formation of Oxide Films on Metals [in Russian] (Izd. AN SSSR, Moscow, 1959).
E. E. Galloni and A. E. Roffo, J. Chem. Phys.9, 875 (1941).
V. V. Andreeva and N. A. Shishakov, Zhur. Fiz. Khim.32, 1671 (1958).
N. K. Andrushchenko and N. A. Shishakov, Zhur. Fiz. Khim.34, 2129 (1959).
N. A. Shishakov, Kristallografiya2, 686 (1957).
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Asanov, U.A., Shishakov, N.A. Mechanism of the reaction of platinum with oxygen at temperatures up to 300‡. Russ Chem Bull 10, 205–209 (1961). https://doi.org/10.1007/BF00919552
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DOI: https://doi.org/10.1007/BF00919552