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Reactions of (chloromethyl) ethoxysilanes with amines

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Amines react with (chloromethyl)ethoxysilanes at 20* at different rates, depending on the nature of the amine.

  2. 2.

    With respect to reactivity, the amines investigated can be arranged in the following series: HOC2H4NH2 >(CH3)3 SiOC2H4NH2> C2H5NH2> > (C2H5)2 NH > C6H5NH2> (C2H5) (C6H5) NH With respect to rate of reaction with amines, (chloromethyl)ethoxysilanes can be arranged in the following series: ClCH2 (CH3)2 SiOC2H5 > ClCH2CH3Si (OC2H5)2 > ClCH2Si (OC2H5)3

  3. 3.

    Two new organosilicon amines were prepared: N-[(ethoxydimethylsilyl)methyl]ethylamine and N-[(diethoxymethylsilyl)methyl]ethylamine.

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Literature cited

  1. F. Boge and H. Post, J. Organ. Chem. 17, 344 (1952).

    Google Scholar 

  2. K. A. Andrianov and L. M. Makarova, Bull. Acad. Sci. USSR, Div. Chem. Sci. 1956, 702.

  3. K. A. Andrianov and M. A. Golubenko, Proc. Acad. Sci. USSR 104, 725 (1955).

    Google Scholar 

  4. J. Noll, J. Speier and B. F. Dauberf, J. Amer. Chem. Soc. 73, 3867 (1951).

    Google Scholar 

  5. British Pat. 686068 (14, 1953); Chem. Abstrs. 48, 3385 a (1954).

  6. K. A. Andrianov and L. M. Volkova, Proc. Acad. Sci. USSR 98, 67 (1954).

    Google Scholar 

  7. P. D. George and J. R. Elliott, J. Amer. Chem. Soc. 77, 3493 (1955).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    K. A. Andrianov & L. M. Volkova

Authors
  1. K. A. Andrianov
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  2. L. M. Volkova
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Andrianov, K.A., Volkova, L.M. Reactions of (chloromethyl) ethoxysilanes with amines. Russ Chem Bull 8, 255–259 (1959). https://doi.org/10.1007/BF00917371

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  • DOI: https://doi.org/10.1007/BF00917371

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