Summary
-
1.
By the action of dialkyl phosphorochloridates on the potassium salts of 4,6,6-trimethyl-6H-1,3-thiazine-2-thiol, 2-benzoxazolethiol, and 2-mercaptobenzothiazole, alkylation products of these compounds were obtained in good yield.
-
2.
Alkylation products of the thiol are formed, again in good yield, by the action of trialkyl phosphites on the disulfides corresponding to these heterocyclic thiols.
Similar content being viewed by others
Literature cited
B. A. Arbuzov and V. M. Zoroastrova, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1958), 1331.
B. P. Lugovkin and B. A. Arbuzov, J. Gen. Chem. 22, 2041 (1962).
J. E. Jansen and R. A. Mathes, J. Am. Chem. Soc. 77, 2866 (1955).
Organic Syntheses (Russian translation), (Foreign Lit. Press, Moscow, 1953), Vol. 4.
I. Heilbron, Dictionary of Organic Compounds (Russian translation) (Foreign Lit. Press, Moscow, 1949), Vol. 2, p. 568.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Arbuzov, B.A., Zoroastrova, V.M. Phosphoric and phosphorothioic esters containing heterocyclic groups. Russ Chem Bull 8, 1001–1004 (1959). https://doi.org/10.1007/BF00916667
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00916667