Skip to main content
SpringerLink
Log in

Structural peculiarities of sodium borosilicate glasses in relation to chemical stability

Communication 3. Structural transformations in sodium borosilicate glasses

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Structural changes in porous glasses obtained from low-alkali sodium borosilicate glasses are found to be directly related to structural changes in the original glass, which depend on composition and heat treatment.

  2. 2.

    The structural transformations occurring in sodium borosilicate glasses consist in the formation of polar [B−(O2)4 Na+ groups, the association of these into borate complexes, changes in the number and dimensions of the complexes, the character of their distribution in the glass and the connections between them.

  3. 3.

    Many of the properties of sodium borosilicate glasses, and the complex nature of the dependence of these on the composition and heat treatment of the glass, are directly or indirectly related to these structural changes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. S. P. Zhdanov and E. V. Koromal'di, Bull. Acad. Sci. USSR, Div. Chem. Sci. 811 (1959).

  2. N. A. Tudorovskaya, Coll. Structure of Glass, pub. Acad. Sci. USSR, (Moscow, 1955), p. 190.

    Google Scholar 

  3. V. A. Florinskaya, Coll. Structure of Glass, pub. Acad. Sci. USSR (Moscow, 1955), p. 70.

    Google Scholar 

  4. E. A. Porai-Koshits, Coll. Structure of Glass, pub. Acad. Sci. USSR, (Moscow, 1955), p. 30

    Google Scholar 

  5. J. Biscoe, C. S. Robinson, and B. E. Warren, J. Am. Ceram, Soc. 22, 180 (1939).

    Google Scholar 

  6. W. A. Weyl, Coll. “Phase Transformations in Solids,” (New York, 1951).

  7. N. V. Belov, Coll. Structure of Glass, pub. Acad. Sci. USSR, (Moscow, 1955), p. 344.

    Google Scholar 

  8. N. V. Belov, Mineralogical Collection of the Lvov Geological Region 8, 13 (1954).

    Google Scholar 

  9. S. P. Zhdanov and E. V. Koromal'di, Bull. Acad. Sci. USSR, Div. Chem. Sci. 626 (1959).

  10. S. P. Zhdanov, Coll. Structure of Glass, pub. Acad. Sci. USSR (Moscow, 1955), p. 162.

    Google Scholar 

  11. B. E. Warren, J. Appl. Phys. 13, 602 (1942).

    Google Scholar 

  12. A. A. Appen, J. Appl. Chem. 26, 569 (1953).

    Google Scholar 

  13. P. L. Myuller, J. Tech. Phys. 25, 236 (1955).

    Google Scholar 

  14. O. S. Molchanova and M. V. Serebryakova, Trans. GOI 23, 141, 3 (1953).

    Google Scholar 

  15. O. S. Molchanova and L. A. Pafomova, Trans. GOI 23, 141, 13 (1953).

    Google Scholar 

  16. O. S. Molchanova, Coll. Structure of Glass, pub. Acad. Sci. USSR (Moscow, 1955), p. 141

    Google Scholar 

  17. L. A. Pafomova, Trans. GOI 24, 145, 201 (1956).

    Google Scholar 

  18. G. Grenier and E. F. Westrum, J. Am. Chem. Soc. 78, 6226 (1956).

    Google Scholar 

  19. Selected Values of Chemical Thermodynamic Properties. Circular of the National Bureau of Standards, 500 (Washington, 1952).

  20. K. K. Kelley, High-temperature Heat-Content, Heat-Capacity and Entropy Data for Inorganic Compounds, Bulletin 476 (Washington, 1949).

    Google Scholar 

  21. E. V. Britsken and A. F. Kapustinskii, Thermodynamic Constants of Inorganic Substances, pub. Acad. Sci. USSR (Moscow, 1949).

    Google Scholar 

  22. O. Kubashevskii and E. Evans, Thermochemistry and Metallurgy (IL, Moscow, 1954).

    Google Scholar 

  23. S. P. Zhdanov, Trans. GOI 24, 145, 86 (1956).

    Google Scholar 

  24. D. P. Dobychin, Coll. Surface Chemical Compounds and Their Role in Adsorption Phenomena, pub. (MGU, Moscow, 1957), p. 166.

    Google Scholar 

  25. G. I. Aleksandrova, V. F. Kiselev, K. G. Krasil'nikov, V. V. Murina, and E. A. Sysoev, Proc. Acad. Sci. USSR 108, 283 (1956).

    Google Scholar 

  26. I. V. Grebenshchikov and O. S. Molchanova, J. Gen. Chem. 12, 588 (1942).

    Google Scholar 

  27. P. L. Myuller, J. Tech. Phys. 26, 2614 (1956).

    Google Scholar 

  28. Tosio Abe, J. Am. Ceram. Soc. 35, 284 (1952).

    Google Scholar 

  29. S. Anderson, R. Bohon, and D. D. Kimpton, J. Am. Ceram. Soc. 38, 370 (1955).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Silicate Chemistry of the Academy of Sciences of the USSR, USSR

    S. P. Zhdanov

Authors
  1. S. P. Zhdanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

In conclusion, the author wishes to thank É. K. Keler for checking through the manuscript and for his advice.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhdanov, S.P. Structural peculiarities of sodium borosilicate glasses in relation to chemical stability. Russ Chem Bull 8, 976–982 (1959). https://doi.org/10.1007/BF00916662

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00916662

Keywords

Search

Navigation