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Synthesis of organic compounds of quinquevalent antimony by the arylation of the organoantimony compounds ArSbX2, and Ar2SbX with diazo compounds

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The arylation of organoantimony compounds of the types ArSbX2 and Ar2SbX with diazo compounds was studied.

  2. 2.

    The most convenient method for the preparation of compounds of the type ArAr'SbX3 is the reaction of aryldiiodostibines with double diazonium-antimony chlorides.

  3. 3.

    A method was developed for the synthesis of compounds of the type Ar2Ar'SbX2 by reaction of Ar2SbX with aryldiazoacetates or double diazonium-metal chlorides.

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Authors and Affiliations

  1. M. V. Lomonosov State University, Moscow

    A. N. Nesmeianov, O. A. Reutov, O. A. Ptitsyna & P. A. Tsurkan

Authors
  1. A. N. Nesmeianov
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  2. O. A. Reutov
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  3. O. A. Ptitsyna
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  4. P. A. Tsurkan
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Nesmeianov, A.N., Reutov, O.A., Ptitsyna, O.A. et al. Synthesis of organic compounds of quinquevalent antimony by the arylation of the organoantimony compounds ArSbX2, and Ar2SbX with diazo compounds. Russ Chem Bull 7, 1384–1392 (1958). https://doi.org/10.1007/BF00914850

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  • DOI: https://doi.org/10.1007/BF00914850

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