Skip to main content
SpringerLink
Log in

Einige Probleme im Zusammenhang mit der direkten Bestimmung der spezifischen Wärmen mittels Differential Scanning-Kalorimetrie

Some problems in connection with the direct determination of specific heats by differential scanning calorimetry

  • Anorganische, Struktur- und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The relation between sample mass andDSC-amplitude was investigated under various experimental conditions for vitreous quartz, both as discs and powders. Contrary to other authors3 proportionality has been found up to the highest masses (75 mg) used.

A statistical analysis of the data indicates that the accuracy of directC p-measurements byDSC can be increased by determining the blank value by extrapolation of the amplitudes for several masses to zero mass instead of using the usual procedure, which involves a run with the empty pans. The overall error ofC p due to instrument errors is estimated not to exceed 2%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. M. J. O'Neill, Analyt. Chem.38, 1331 (1966).

    Google Scholar 

  2. E. S. Watson, M. J. O'Neill, J. Justin undN. Brenner, Analyt. Chem.36, 1233 (1964).

    Google Scholar 

  3. D. Vučelić, V. Vučelić undN. Juranić, J. Thermal Anal.5, 459 (1973).

    Google Scholar 

  4. L. G. Berg undV. G. Egunov, J. Thermal Anal2, 53 (1970).

    Google Scholar 

  5. A. P. Gray, in:R. S. Porter undJ. F. Johnson (hrsg.), Analytical Calorimetry, Vol. I, S. 209. New York: Plenum Press. 1968.

    Google Scholar 

  6. M. J. Richardson undP. Burrington, J. Thermal Anal.6, 351 (1974).

    Google Scholar 

  7. A. J. Dash, Arthur Finch, P. J. Gardner undM. Cottrell, J. Chem. Engng. Data19, 113 (1974).

    Google Scholar 

  8. J. Mikler, H. Ipser undK. L. Komarek, Mh. Chem.105, 977 (1974).

    Google Scholar 

  9. M. J. O'Neill, Analyt. Chem.36, 1238 (1964).

    Google Scholar 

  10. M. J. O'Neill undR. L. Fyans, Design of Differential Scanning Calorimeters and the Performance of a New System (Paper presented at the Eastern Analytical Symposium, New York, 1971), Perkin-Elmer Reprint, Order No. MA-9.

  11. E. Hardtwig, Fehler- und Ausgleichsrechung (B. I. Hochschultaschenbuch 262/262a) S. 46 und 133. Mannheim-Wien-Zürich Bibliographisches Institut. 1968.

    Google Scholar 

  12. E. Kreyszig, Statistische Methoden und ihre Anwendungen, 4. Aufl., S. 239 ff. Göttingen: Vanderhoeck & Ruprecht. 1973.

    Google Scholar 

  13. E. Hardtwig, l. c. S. 127. Mannheim—Wien—Zürich Bibliographisches Institut.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie der Universität Wien, Währinger Straße 42, A-1090, Wien, Österreich

    Johann Mikler & Erich Reiffenstein

Authors
  1. Johann Mikler
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Erich Reiffenstein
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Mit 2 Abbildungen

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mikler, J., Reiffenstein, E. Einige Probleme im Zusammenhang mit der direkten Bestimmung der spezifischen Wärmen mittels Differential Scanning-Kalorimetrie. Monatshefte für Chemie 106, 85–96 (1975). https://doi.org/10.1007/BF00914502

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00914502

Search

Navigation