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Isomerization of 3,4-epoxyphospholanes

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the presence of catalysts of basic character, 3,4-epoxyphospholanes are isomerized to 2-phospholen-4-ols.

  2. 2.

    Unsymmetrical 3,4-epoxyphospholanes form a mixture of isomers, with a substantial predominance of the isomer containing a tertiary hydroxyl group.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, A. P. Rakov & A. O. Vizel'

Authors
  1. B. A. Arbuzov
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  2. A. P. Rakov
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  3. A. O. Vizel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 85–90, January, 1970.

In conclusion the authors sincerely express their gratitude to Z. G. Isaeva for a number of valuable suggestions, made during the course of the work and in interpreting the results.

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Arbuzov, B.A., Rakov, A.P. & Vizel', A.O. Isomerization of 3,4-epoxyphospholanes. Russ Chem Bull 19, 78–82 (1970). https://doi.org/10.1007/BF00913928

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  • DOI: https://doi.org/10.1007/BF00913928

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