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Effect of the treatment of chromic oxide with hydrogen and oxygen on its catalytic activity in dehydrogenation and dehydration reactions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

We determined the activation energies of the dehydrogenation of cyclohexane and the dehydrogenation and dehydration of isopropyl alcohol on chromic oxide that had been subjected to various preliminary treatments, namely, with hydrogen and air separately and a combination of the two. From these data we found the energies of the bonds of hydrogen, carbon, and oxygen with the surface of chromic oxide. Information was obtained on the comparative sizes of the catalytically active surfaces of the catalyst.

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Authors and Affiliations

  1. S. Ordzhonikidze Aviation Institute, Moscow and N.D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    A. A. Tolstopya Tova, A. A. Balandin & K. A. Dulitskaya

Authors
  1. A. A. Tolstopya Tova
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  2. A. A. Balandin
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  3. K. A. Dulitskaya
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Tova, A.A.T., Balandin, A.A. & Dulitskaya, K.A. Effect of the treatment of chromic oxide with hydrogen and oxygen on its catalytic activity in dehydrogenation and dehydration reactions. Russ Chem Bull 8, 1646–1653 (1959). https://doi.org/10.1007/BF00912098

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  • DOI: https://doi.org/10.1007/BF00912098

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