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Synthesis of vinyl esters of unsaturated acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the vinylation of unsaturated acids with vinyl acetate in the presence of a mixed catalyst, composed of boron trifluoride etherate and mercury acetate. The vinyl esters of vinylacetic, acrylic, crotonic (trans), cinnamic (trans), propiolic, phenylpropiolic, trimethylsilylpropiolic and dimethylethylsilylpropiolic acids were synthesized.

  2. 2.

    The Raman spectra of a number of the synthesized vinyl esters were obtained.

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Literature cited

  1. U.S. Patent 2,344, 798 (1944); Chem. Abstrs.,38, 3665 (1944).

  2. U.S. Patent 2,363,286 (1944); Chem. Abstrs.,39, 3178 (1945).

  3. German Patent 1,127,888 (1962); RZhKhim. 2H38P (1964).

  4. M. F. Shostakovskii and L. I. Komarova, Zh. Prikl. Khimii,39, 725 (1966).

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  5. M. J. Shostakovskii and L. I. Komarova, Avt. Svid. [a form of Russian patent] No. 166,329; Byull. Izobr., No. 22 (1964).

  6. Dictionary of Organic Compounds [Russian translation], IL (1949).

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Section of the Academy of Sciences of the USSR, USSR

    M. F. Shostakovskii, L. I. Komarova, A. Kh. Filippova & G. V. Ratovskii

Authors
  1. M. F. Shostakovskii
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  2. L. I. Komarova
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  3. A. Kh. Filippova
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  4. G. V. Ratovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2526–2530, November, 1967.

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Shostakovskii, M.F., Komarova, L.I., Filippova, A.K. et al. Synthesis of vinyl esters of unsaturated acids. Russ Chem Bull 16, 2403–2405 (1967). https://doi.org/10.1007/BF00911853

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  • DOI: https://doi.org/10.1007/BF00911853

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