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Conclusions

  1. 1.

    The oxide ring in functionally substituted α-oxides is reliably characterized by absorption in the region of 1240–1260 cm−1.

  2. 2.

    The oxide ring is capable of conjugation with the π-electrons of the double bond, if it is situated between double bonds or between a double bond and a group capable for conjugation.

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Literature cited

  1. B. I. Kozyrkin, L. A. Yanovskaya, and V. F. Kucherov, Izv. AN SSSR, Ser. Khimi.,1966, 683.

  2. L. A. Yanovskaya, B. I. Kozyrkin, and V. F. Kucherov, Izv. AN SSSR, Ser. Khimi.,1966, 1595.

  3. A. Bosowsky, Ethylene Oxide, see Heterocyclic Compounds with Three- and Four-Membered Rings (ed A. Weissberger), New York (1964).

  4. L. A. Yanovskaya, R. N. Stepanova, G. A. Kogan, and V. F. Kucherov, Izv. AN SSSR, Ser. Khimi.,1964, 857.

  5. B. G. Kovalev, L. A. Yanovskaya, V. F. Kucherov, and G. A. Kogan, Izv. AN SSSR, Otd. Khim., N.,1963, 145.

  6. L. A. Yanovskaya, R. N. Stepanova, G. A. Kogan, and V. F. Kucherov, Izv. AN SSSR, Otd. Khim., N.,1963, 857.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2432–2435, November, 1967.

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Yanovskaya, L.A., Kozyrkin, B.I., Kogan, G.A. et al. Infrared spectra of functionally substituted oxides. Russ Chem Bull 16, 2319–2321 (1967). https://doi.org/10.1007/BF00911835

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  • DOI: https://doi.org/10.1007/BF00911835

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