Skip to main content
Log in

Condensation of chloral with phosphoramidic esters, and some properties of the compounds obtained

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Some dialkyl phosphoramidates were prepared and characterized.

  2. 2.

    Chloral adducts of dialkyl alkylphosphoramidates were prepared and characterized.

  3. 3.

    Under the action of triethylamine dialkyl alkyl(2,2,2-trichloro-1-hydroxyethyl)phosphoramidates break down with formation of dialkyl alkylformylphosphoramidates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. U. S. Patent No. 2,735,285; Chem. Abs.,50, 15032g (1956).

  2. J. La Rocca, J. Leonard, and W. Weaver, J. Org. Chem.,16, 47 (1951).

    Google Scholar 

  3. Austrian Patent No. 197,351; Chem. Zentr.,1960, 2671.

  4. H. Bohme, F. Eiden, and D. Schunemann, Arch. Pharmaz. Ber., Deutsch. Pharmaz. Ges.,294/66, 307 (1961); Chem. Zentr.,1961, 15354.

    Google Scholar 

  5. J. Lichtenberger, J.-P. Fleury, and B. Barette, Bull. Soc. chim.,1955, 669.

  6. P. I. Alimov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1961, 61.

  7. West German Patent No. 1,052,984; Chem. Zentr.,1959, 15191.

  8. B. C. Saunders, C. J. Stacey, F. Wild, and J. G. B. Wilding, J. Chem. Soc.,1948, 699.

  9. R. A. Chittenden and L. C. Thomas, Spectrochim. Acta,22, 1449 (1966).

    Google Scholar 

  10. Filler, J. Am. Chem. Soc.,75, 1376 (1954).

    Google Scholar 

  11. L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963), p. 303.

  12. M. I. Kabachnik and V. A. Gilyarov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1961, 816.

  13. A. Michaelis, Liebigs Ann.,407, 290 (1915).

    Google Scholar 

  14. W. S. Wadsworth and W. D. Emmon, J. Org. Chem.,29, 2816 (1964).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 587–593, March, 1968.

We thank R. R. Shagidullin for valuable advice and help in the interpretation and discussion of the IR spectra.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nikonorov, K.V., Gurylev, É.A. & Chernova, A.V. Condensation of chloral with phosphoramidic esters, and some properties of the compounds obtained. Russ Chem Bull 17, 569–573 (1968). https://doi.org/10.1007/BF00911613

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00911613

Keywords

Navigation