Skip to main content
SpringerLink
Log in

Reactions with transfer of electrons

Communication 4. Triphenylchloromethane as an electron acceptor

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The interaction of the dipotassium salt of the cyclooctatetraene dianion with triphenylchloromethane is accompanied by a transfer of electrons, with the formation of cyclooctatetraene. At the same time, the triphenylmethyl anion (if the donor and acceptor interact in equivalent amounts) or the triphenylmethyl radical (when the amount of the acceptor is twice the equivalent amount) arises.

  2. 2.

    The interaction of triphenylmethylpotassium with cyclooctatetraene was accompanied by a transfer of electrons and is reversible.

  3. 3.

    The interaction of equivalent amounts of the dipotassium salt of the tetraphenylethylene dianion and triphenylchloromethane is accompanied by a transfer of electrons. As a result tetraphenylethylene and the triphenylmethyl anion are formed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. D. N. Kursanov and Z. V. Todres, Dokl. Akad. Nauk SSSR,172, 1086 (1967).

    Google Scholar 

  2. D. N. Kursanov, Z. V. Todres, N. T. Ioffe, and Z. N. Parnes, Dokl. Akad. Nauk SSSR,174, 358 (1967).

    Google Scholar 

  3. D. N. Kursanov, Z. V. Todres, Yu. I. Lyakhovetskii, and Z. G. Dremina, Izv. Akad. Nauk SSSR, Ser, Khim.,1967, 2197.

  4. T. S. Cantrell and H. Shechter, J. Amer. Chem. Soc.,85, 3300 (1963).

    Google Scholar 

  5. D. A. Bak and K. Conrow, J. Organ. Chem.,31, 3958 (1966).

    Google Scholar 

  6. V. D. Azatyan, Materials of the Scientific Conference of the Institutes of Chemistry of the Academy of Science of the Azerbaidzhan, Armenian and Georgian SSSR [in Russian], Izdo-vo AN ArmSSR, Erevan (1962), p. 241; Chem. Abstrs.,58, 11230f (1963).

    Google Scholar 

  7. G. Wittig and D. Wittenberg, Liebigs Ann. Chem.,606, 1 (1957).

    Google Scholar 

  8. K. Allendoerfer and Ph. Rieger, J. Amer. Chem. Soc.,87, 2336 (1965).

    Google Scholar 

  9. S. Wawsonek, J. Amer. Chem. Soc.,68, 254 (1946).

    Google Scholar 

  10. I. Schmidlin and A. Garsia-Banus, Ber.,45, 1344 (1912).

    Google Scholar 

  11. W. Schlenk and H. Mark, Ber.,55, 2289 (1922).

    Google Scholar 

  12. V. Sandel and H. Freedman, J. Amer. Chem. Soc.,85, 2328 (1963).

    Google Scholar 

  13. R. Levine and E. Braumgarten, J. Amer. Chem. Soc.,66, 1230 (1944).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    Z. V. Todres, N. T. Ioffe & D. N. Kursanov

Authors
  1. Z. V. Todres
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. T. Ioffe
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. N. Kursanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 523–526, March, 1968.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Todres, Z.V., Ioffe, N.T. & Kursanov, D.N. Reactions with transfer of electrons. Russ Chem Bull 17, 511–513 (1968). https://doi.org/10.1007/BF00911601

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00911601

Keywords

Search

Navigation