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Homogeneous destructive hydrogenation of tetralin at high pressures of hydrogen

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The homogeneous destructive hydrogenation of tetralin (1,2,3,4-tetrahydronaphthalene) was investigated at 440–462° and at pressures of up to 1200 atm.

  2. 2.

    A general scheme is proposed for the transformations of tetralin under the conditions studied; it is based on the investigation of the reaction products by fractional-distillation and Raman-spectrum methods, and also on kinetic data.

  3. 3.

    The results are in accord with the views expounded in the paper on the radical-chain mechanism of the homogeneous destructive hydrogenation of aromatic hydrocarbons.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry and Spectroscopy Commission of the Division of Physical and Mathematical Sciences of the Academy of Sciences of the USSR, USSR

    A. E. Gavrilova, M. G. Gonikberg, V. T. Aleksanian & Kh. E. Sterin

Authors
  1. A. E. Gavrilova
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  2. M. G. Gonikberg
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  3. V. T. Aleksanian
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  4. Kh. E. Sterin
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Gavrilova, A.E., Gonikberg, M.G., Aleksanian, V.T. et al. Homogeneous destructive hydrogenation of tetralin at high pressures of hydrogen. Russ Chem Bull 7, 952–959 (1958). https://doi.org/10.1007/BF00911346

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  • DOI: https://doi.org/10.1007/BF00911346

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