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Komplexe des zweiwertigen Molybdäns, Derivate des Oktahalodimolybdat(II)-Ions, 1. Mitt.: Chlorokomplexe mit Pyridin, 2,2′-Dipyridyl und 1,10-Phenanthrolin

Coordination compounds of molybdenum(II), derivatives of the octahalodimolybdate(II) ion. I. Chlorocomplexes with pyridine, 2.2′-bipyridine, and 1.10-phenanthroline

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Octachlorodimolybdate(II) ion reacts with pyridine giving a compound of stoichiometry Mo2Cl4(C5H5N)4. This compound reacts at 120 °C in the absence of oxygen with 2.2′-bipyridine and 1.10-phenanthroline, giving Mo2Cl4(C10H8N2)2 and Mo2Cl4(C12H8N2)2, resp. Magnetic measurements, IR spectra and chemical evidence are used for the identification of the new compounds.

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Authors and Affiliations

  1. Laboratorium für anorganische Chemie der Universität Ljubljana, P.O. Box 537, YU-61001, Ljubljana, Jugoslawien

    J. V. Brenčič, D. Dobčnik & P. Šegedin

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  1. J. V. Brenčič
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  2. D. Dobčnik
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  3. P. Šegedin
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Brenčič, J.V., Dobčnik, D. & Šegedin, P. Komplexe des zweiwertigen Molybdäns, Derivate des Oktahalodimolybdat(II)-Ions, 1. Mitt.: Chlorokomplexe mit Pyridin, 2,2′-Dipyridyl und 1,10-Phenanthrolin. Monatshefte für Chemie 105, 142–147 (1974). https://doi.org/10.1007/BF00911299

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  • DOI: https://doi.org/10.1007/BF00911299

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