Skip to main content
SpringerLink
Log in

Molybdate Complexes of Neptunium(V) with Cations K+, NH4+, Rb+, and Tl+ in Outer Sphere

  • Published:
Radiochemistry Aims and scope

Abstract

We have synthesized and structurally characterized molybdate complexes of neptunium(V) with singly charged cations in the outer sphere and the ratio NpO2+ : MoO42– = 1 : 1 of the common composition M[(NpO2)(MoO4)(H2O)] (I), where M+ = NH4+ (Ia), Rb+ (Ib) and Tl+ (Ic), and a new complex with the ratio NpO2+ : MoO42– = 1 : 2 of the composition K6[(NpO2)(MoO4)2(H2O)2]2 (II). In isostructural compounds I, the coordination environment of Np atoms is pentagonal bipyramids linked by tetradentate-bridging MoO42– ions into an anionic framework. The main structural motive of compound II is centrosymmetric dimeric anions, in which pentagonal bipyramids are linked by bidentate bridging MoO42– ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Grigor’ev, M.S., Charushnikova, I.A., and Fedoseev, A.M., Radiochemistry, 2020, vol. 62, no. 4, p. 465. https://doi.org/10.1134/S1066362220040037

    Article  Google Scholar 

  2. Grigor’ev, M.S., Baturin, N.A., Fedoseev, A.M., and Budantseva, N.A., Koord. Khim., 1994, vol. 20, no. 7, p. 552.

    Google Scholar 

  3. Grigor’ev, M.S., Charushnikova, I.A., and Fedoseev, A.M., Radiochemistry, 2021, vol. 63 no. 4, p. 413. https://doi.org/10.1134/S1066362221040032

    Article  Google Scholar 

  4. Grigor’ev, M.S., Charushnikova, I.A., and Fedoseev, A.M., Radiochemistry, 2020, vol. 62, no. 5, p. 617. https://doi.org/10.1134/S1066362220050082

    Article  Google Scholar 

  5. Grigor’ev, M.S., Charushnikova, I.A., Fedoseev, A.M., Budantseva, N.A., Yanovskii, A.I., and Struchkov, Yu.T., Radiokhimiya, 1992, vol. 34, no. 5, p. 7.

    Google Scholar 

  6. Grigor’ev, M.S., Charushnikova, I.A., Fedoseev, A.M., Budantseva, N.A., Baturin, N.A. and Regel, L.L., Radiokhimiya, 1991, vol. 33, no. 4, p. 19.

    Google Scholar 

  7. Grigor’ev, M.S., Fedoseev, A.M., Budantseva, N.A., and Antipin, M.Yu., Radiokhimiya, 2005, vol. 47, no. 6, p. 500. https://doi.org/10.1134/S1066362221020016

    Article  Google Scholar 

  8. Grigor’ev, M.S., Charushnikova, I.A., and Fedoseev, A.M., Radiochemistry, 2021, vol. 63, no. 2, p. 133. https://doi.org/10.1134/S1066362221020016

    Article  Google Scholar 

  9. Budantseva, N.A., Grigor’ev, M.S., Fedoseev, A.M., Radiochemistry, 2015, vol. 57, no. 3, p. 225. https://doi.org/10.1134/S1066362221020016

    Article  CAS  Google Scholar 

  10. Sheldrick, G.M., SADABS. Madison, Wisconsin (USA): Bruker AXS, 2008.

    Google Scholar 

  11. Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, no. 1, pp. 112–118.

    Article  CAS  Google Scholar 

  12. Sheldrick, G.M., Acta Crystallogr. Sect. C, 2015, vol. 71, no. 1, pp. 3–8.

    Article  Google Scholar 

Download references

Funding

The study was in part financed by the Ministry of Science and Higher Edication of the Russian Federation (topic no. AAAA-A18-118040590105-4) and by the program 35 of the Presidium of the Russian Academy of Sciences “Scientific foundations of the development of new functional materials.” X-ray diffraction experiments were performed at the Center for Collective Use of Physical Methods of Investigation of the Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences.

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    M. S. Grigor’ev, I. A. Charushnikova & A. M. Fedoseev

Authors
  1. M. S. Grigor’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. A. Charushnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Fedoseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Charushnikova.

Ethics declarations

The authors declare no conflicts of interest.

Additional information

Translated from Radiokhimiya, No. 5, pp. 431–439, April, 2021 https://doi.org/10.31857/S0033831121050026

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Grigor’ev, M.S., Charushnikova, I.A. & Fedoseev, A.M. Molybdate Complexes of Neptunium(V) with Cations K+, NH4+, Rb+, and Tl+ in Outer Sphere. Radiochemistry 63, 556–564 (2021). https://doi.org/10.1134/S1066362221050027

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1066362221050027

Keywords:

Search

Navigation