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Synthesis of 1,4- and 1,5-bis(dighlorobutyl)pentanes from the hydroboronation product of piperylene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have obtained 1-chloro-2-methylboracyclopentane, 1-chloroboracyclohexane, 1,4-bis(dichloroboryl)pentane and 1,5-bis-(dichloroboryl)pentane from the hydroboronation product of piperylene and BCl3.

  2. 2.

    1-Chloro-2-methylboracyclopentane isomerizes to 1-chloroboracyclohexane when heated.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khlmicheskaya, No. 5, pp. 1070–1076, May, 1968.

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Zakharkin, L.I., Kovredov, A.I. Synthesis of 1,4- and 1,5-bis(dighlorobutyl)pentanes from the hydroboronation product of piperylene. Russ Chem Bull 17, 1017–1022 (1968). https://doi.org/10.1007/BF00910835

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  • DOI: https://doi.org/10.1007/BF00910835

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