Abstract
The half-wave potentials of the alkali metal ions and of the barium ion vs. the half-wave potential of bisbiphenyl-chromium(I) have been determined in 0.1m-solutions of tetraethylammonium perchlorate in benzonitrile, acetonitrile, propandiol-1.2-carbonate, methanol and water at 25°C. For each redox pair the relationship between half-wave potential and solvent donicity has been established.
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Duschek, O., Gutmann, V. Der Lösungsmitteleinfluß auf die polarographische Reduktion der Alkalimetallionen und des Bariumions. Monatshefte für Chemie 104, 1259–1268 (1973). https://doi.org/10.1007/BF00910040
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DOI: https://doi.org/10.1007/BF00910040