Abstract
In the nearly unknown class of cyclosilanes with one heteroatom, decaphenyl-oxa-cyclohexasilane was prepared for the first time by removing of water. The diol was prepared by hydrolysis of the corresponding 1,5-dichlorocompound. Cyclisation was not successful with 1,5-Di(ethylamine)decaphenylpentasilane, which was prepared also for the first time. Spectroscopic data were determined of all synthesized compounds.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literatur
E. Carberry undB. D. Dombek, J. Organomet. Chem.22 C, 43 (1970).
H. Gilman, D. J. Peterson, A. W. J. Jarvie undH. J. S. Winkler, J. Amer. Chem. Soc.82, 2076 (1960).
F. S. Kipping, J. Chem. Soc.123, 2598 (1923).
E. Hengge undU. Brychcy. Mh. Chem.97, 1309 (1966).
E. Hengge undD. Wolfer, J. Organomet. Chem.66, 413 (1974).
E. Hengge undD. Wolfer, Angew. Chem.85, 304 (1973).
H. Gilman undD. R. Chapman, J. Organomet. Chem.8, 451 (1967).
H. Gilman undG. L. Schwebke, J. Amer. Chem. Soc.86, 2693 (1964).
Author information
Authors and Affiliations
Additional information
Herrn Prof. Dr.G. Zigeuner zum 60. Geburtstag gewidmet.
Rights and permissions
About this article
Cite this article
Hengge, E., Stüger, H. Zur Darstellung sechsgliedriger Cyclosilane mit einem Heteroatom. Monatshefte für Chemie 111, 1043–1051 (1980). https://doi.org/10.1007/BF00909660
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00909660