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Massenspektrometrische Untersuchungen von PhthalocyaninenPc—MeX n

Mass spectrometric investigation of phthalocyanines Pc−MeXn

  • Organische Chemie und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

PhthalocyaninesPc−Me(III)X andPc−Me(V)X 3 were obtained by reacting anhydrous metal halides with phthalodinitrile and di-lithium-phthalocyanine, resp. A phthalocyanine containing niobium(V) was prepared for the first time. Mass spectrometric investigation of the products formed show the molecular ion in the case of chloro-aluminum-, chloro-indium- and tribromo-niobium-phthalocyanine. The mass spectra of chloro-scandium-, chloro-yttrium- and tribromo-tantalum-phthalocyanine showed neither peaks of the molecular mass nor metal containing fragments of the phthalocyanine structure. Mass spectrometric results seem to depend critically on the purity of the compounds employed.

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Authors and Affiliations

  1. Instituten für Allgemeine Chemie und für Anorganische Chemie der Technischen Hochschule Wien, Lehárgasse 4, A-1060, Wien, Österreich

    K. Varmuza, G. Maresch & A. Meller

  2. Anorganisch-Chemischen Institut der Universität Göttingen, Bundesrepublik Deutschland

    K. Varmuza, G. Maresch & A. Meller

Authors
  1. K. Varmuza
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  2. G. Maresch
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  3. A. Meller
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Varmuza, K., Maresch, G. & Meller, A. Massenspektrometrische Untersuchungen von PhthalocyaninenPc—MeX n . Monatshefte für Chemie 105, 327–333 (1974). https://doi.org/10.1007/BF00907380

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  • DOI: https://doi.org/10.1007/BF00907380

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