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Synthesis and properties of lithium peroxide monoperoxyhydrate Li2O2·H2O2

  • Inorganic and Analytical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The decomposition of Li2O2·H2O2·2H2O to lithium peroxide at 50 and 75°C proceeds with intermediate formation of the compounds Li2O2·H2O2·H2O and Li2O2·H2O2.

  2. 2.

    Optimum conditions for the synthesis of Li2O2·H2O2 were found.

  3. 3.

    It was shown by the PMR method that the compound Li2O2·H2O2 (or lithium hydroperoxide, LiOOH) has a lithium peroxide monoperoxyhydrate structure.

  4. 4.

    Compounds with the composition Li2O2·H2O2·2H2O and Li2O2·2H2O2 also should be considered as products of crystallization addition of H2O2 and H2O to Li2O2.

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Authors and Affiliations

  1. N.S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    T. A. Dobrynina, N. A. Akhapkina & V. F. Chuvaev

Authors
  1. T. A. Dobrynina
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  2. N. A. Akhapkina
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  3. V. F. Chuvaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 493–496, March, 1969.

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Dobrynina, T.A., Akhapkina, N.A. & Chuvaev, V.F. Synthesis and properties of lithium peroxide monoperoxyhydrate Li2O2·H2O2 . Russ Chem Bull 18, 438–440 (1969). https://doi.org/10.1007/BF00906954

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  • DOI: https://doi.org/10.1007/BF00906954

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