Skip to main content
SpringerLink
Log in

Präparation und röntgenographische Untersuchung eines neuen Kupfer-Oxoaluminats: Cu2Al4O7

Preparation and X-ray investigation of a new compound Cu2Al4O7

  • Inorganic and Physical Chemistry
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Solid state reaction of CuO and Al2O3 with a flux of PbO about 930°C and reaction time of 8d gives the new compound Cu2Al4O7. The red single crystals were examined by energydispersive microanalysis and X-ray diffraction methods. Cu2Al4O7 has cubic symmetry, space group\(F\bar 43m\),a=908.0 pm. The typical coordination of Cu+ (CN=6 and CN=12) and the interstitial arrangement of the AlO4-tetrahedra are discussed with respect to related compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Müller-Buschbaum, Hk., Angew. Chem.89, 704 (1977).

    Google Scholar 

  2. Hestermann, K., Hoppe, R., Z. anorg. allg. Chem.360, 113 (1968).

    Google Scholar 

  3. Hoppe, R., 20 Jahre Fonds der Chem. Industrie (Verband der Chem. Industrie Frankfurt, Hrsg.), S. 97. Weinheim: Verlag Chemie. 1970.

    Google Scholar 

  4. Haas, H., Kordes, E., Z. Krist.129, 259 (1969).

    Google Scholar 

  5. Bertaut, E. F., Delorme, C., C. R. heb. séances Acad. Sci.238, 1829 (1954).

    Google Scholar 

  6. Shannon, R. D., Rogers, D. B., Prewitt, C. T., Inorg. Chem.10, 713 (1971).

    Google Scholar 

  7. Teske, Chr., Müller-Buschbaum, Hk., Z. anorg. allg. Chem.379, 113 (1970).

    Google Scholar 

  8. Teske, Chr., Müller-Buschbaum, Hk., Z. Naturforsch.27 b, 296 (1972).

    Google Scholar 

  9. Christian, H. P., Müller-Buschbaum, Hk., Z. Naturforsch.30 b, 175 (1975).

    Google Scholar 

  10. Meyer, Hj., Dissertation, Kiel 1980.

  11. Krause, O., Thiel, W., Z. anorg. allg. Chem.203, 120 (1931).

    Google Scholar 

  12. Holgersson, S., Z. anorg. allg. Chem.204, 378 (1932).

    Google Scholar 

  13. Cooley, R. F., Reer, J. S., J. Amer. Ceram. Soc.55, 345 (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, D-2300, Kiel, Bundesrepublik Deutschland

    Hansjörg Meyer & Hanskarl Müller-Buschbaum

Authors
  1. Hansjörg Meyer
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hanskarl Müller-Buschbaum
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Meyer, H., Müller-Buschbaum, H. Präparation und röntgenographische Untersuchung eines neuen Kupfer-Oxoaluminats: Cu2Al4O7 . Monatshefte für Chemie 112, 51–57 (1981). https://doi.org/10.1007/BF00906242

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00906242

Key words

Search

Navigation