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Proportions of isomers in the cyanation of methyl-, ethyl-, and phenyl-ferrocenes

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    By the method of gas-liquid chromatography the proportions of isomers were determined in the mixtures of nitriles formed in the cyanation of methyl-, ethyl-, and phenyl-ferrocenes. The most reactive position is the position adjacent to the substituent.

  2. 2.

    The alkaline hydrolysis of the isomeric ethyl and phenyl-ferrocenecarbonitriles to amides was investigated. The least reactive isomer is the 1,2-isomer.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, L. P. Yur'eva & É. G. Perevalova

Authors
  1. A. N. Nesmeyanov
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  2. L. P. Yur'eva
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  3. É. G. Perevalova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 578–582, March, 1967.

We sincerely thank S. V. Vitt for help in the work.

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Nesmeyanov, A.N., Yur'eva, L.P. & Perevalova, É.G. Proportions of isomers in the cyanation of methyl-, ethyl-, and phenyl-ferrocenes. Russ Chem Bull 16, 557–560 (1967). https://doi.org/10.1007/BF00905991

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  • DOI: https://doi.org/10.1007/BF00905991

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