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On the relationship between the aprotonic acidity of aluminum oxide and its catalytic activity in the reaction of hydrogen transfer

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The activity of aluminum oxide in the reaction of hydrogen transfer from an alcohol molecule to a ketone is determined by its aprotonic acidity.

  2. 2.

    The aprotonic portions of aluminum oxide catalyze the reaction of hydrogen transfer at relatively low temperatures (100–150°), at which dehydration of the alcohol does not yet take place.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    L. Kh. Freidlin, V. Z. Sharf & E. N. German

Authors
  1. L. Kh. Freidlin
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  2. V. Z. Sharf
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  3. E. N. German
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 777–780, April, 1968.

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Freidlin, L.K., Sharf, V.Z. & German, E.N. On the relationship between the aprotonic acidity of aluminum oxide and its catalytic activity in the reaction of hydrogen transfer. Russ Chem Bull 17, 749–751 (1968). https://doi.org/10.1007/BF00905745

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  • DOI: https://doi.org/10.1007/BF00905745

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