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Catalysts Pt/(Ga)Al2O3 Obtained Using Aluminum Metal Activated with Gallium

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Abstract

The products of the interaction of activated aluminum with water were used as a precursor of an oxide support of catalysts. The possibility of changing the composition of the oxide phase by varying the nature of the activator (gallium and Ga—In eutectic alloy) is shown. It was found that during the synthesis, gallium cations enter the structure of aluminum oxide by displacing aluminum from the tetrahedral position. The effect of gallium content in the composition of the support on its textural and acid-base properties is demonstrated. The presence of gallium in the composition of the catalyst leads to a modification of the catalytic properties of platinum, which consists in suppressing the hydrogenolysis of C—C bonds in the reaction of propane conversion.

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Acknowledgments

The authors are grateful to L.N. Stepanova, V.P. Talzy, O.V Mayevskaya, I.V. Muromtsev, A.V. Shilova, and R.R. Izmailov for their participation in the study of the samples.

Funding

This work was carried out as part of the state assignment of the Institute of Catalysis of the SB RAS, project no. AAAA-A17-117041110045-9.

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Authors and Affiliations

  1. Center for New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis of Siberian Branch of the Russian Academy of Sciences, Omsk, 644040, Russia

    O. B. Belskaya, T. I. Gulyaeva & N. N. Leont’eva

  2. Federal Research Center Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    A. I. Nizovskii & V. I. Bukhtiyarov

  3. Omsk State Technical University, Omsk, 644050, Russia

    O. B. Belskaya & A. I. Nizovskii

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  1. O. B. Belskaya
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  2. A. I. Nizovskii
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  3. T. I. Gulyaeva
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  4. N. N. Leont’eva
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  5. V. I. Bukhtiyarov
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Correspondence to O. B. Belskaya.

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Russian Text © The Author(s), 2020, published in Zhurnal Prikladnoi Khimii, 2020, Vol. 93, No. 1, pp. 132–141.

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Belskaya, O.B., Nizovskii, A.I., Gulyaeva, T.I. et al. Catalysts Pt/(Ga)Al2O3 Obtained Using Aluminum Metal Activated with Gallium. Russ J Appl Chem 93, 118–126 (2020). https://doi.org/10.1134/S1070427220010139

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  • DOI: https://doi.org/10.1134/S1070427220010139

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