Conclusions
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1.
The kinetics of the interaction of triethyl phsophite with a series of phenolic Mannich bases was studied in tetralin and dimethylformamide at various initial concentrations and temperatures. The order, constants, and activation energies of the corresponding reactions were determined.
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2.
The limiting step of the reaction of triethyl phosphite with phenolic Mannich bases is monomolecular decomposition of the latter, with an elimination of diethylamine.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya khimicheskaya, No. 4, pp. 768–772, April, 1968.
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Ivanov, B.E., Valitova, L.A. & Vavilova, T.G. Kinetics of the interaction of phenolic Mannich bases with triethyl phosphite. Russ Chem Bull 17, 741–744 (1968). https://doi.org/10.1007/BF00905743
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DOI: https://doi.org/10.1007/BF00905743