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Addition of triethylsilyllithium and triethylgermyllithium to multiple bonds

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Triethylsilyllithium and triethylgermyllithium add not only to phenylated multiple bonds (styrene, trans-stilbene, phenylacetylene, tolan), but also to the unactivated multiple bonds of ethylene, propylene, and 1-hexene.

  2. 2.

    The lithium atom in the formed adducts can be replaced by hydrogen when reacted with water, or by the (C2H5)3Ge group in the reactions with triethylbromogermane.

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Authors and Affiliations

  1. Laboratory of Polymer Stabilization, Academy of Sciences of the USSR, USSR

    N. S. Vyazankin, E. N. Gladyshev, E. A. Arkhangel'skaya, G. A. Razuvaev & S. P. Korneva

Authors
  1. N. S. Vyazankin
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  2. E. N. Gladyshev
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  3. E. A. Arkhangel'skaya
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  4. G. A. Razuvaev
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  5. S. P. Korneva
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Additional information

Translated from Izvestiya Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2081–2085, September, 1968. Original article submitted

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Vyazankin, N.S., Gladyshev, E.N., Arkhangel'skaya, E.A. et al. Addition of triethylsilyllithium and triethylgermyllithium to multiple bonds. Russ Chem Bull 17, 1975–1978 (1968). https://doi.org/10.1007/BF00904996

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  • DOI: https://doi.org/10.1007/BF00904996

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