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Homolytic telomerization of vinyl acetate with tetrachloroethylene at high pressures

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    At atmospheric pressure the reaction of vinyl acetate with tetrachloroethylene in presence of azodiisobutyronitrile at 65° is a telomerization reaction. When the reaction is carried out under a pressure of 4000 kg/sq. cm, the average number of tetrachloroethylene units in the molecules of the solid reaction products is two, which indicates that a copolymerization process is also occurring.

  2. 2.

    The relations found for the effect of pressure on the reaction studied are explained in terms of concepts of the theory of the transition state.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    V. M. Zhulin, M. G. Gonikberg & V. N. Zagorbinina

Authors
  1. V. M. Zhulin
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  2. M. G. Gonikberg
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  3. V. N. Zagorbinina
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Additional information

The mechanic A. A. Yablonskii took part in the work.

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Zhulin, V.M., Gonikberg, M.G. & Zagorbinina, V.N. Homolytic telomerization of vinyl acetate with tetrachloroethylene at high pressures. Russ Chem Bull 11, 663–666 (1962). https://doi.org/10.1007/BF00904772

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  • DOI: https://doi.org/10.1007/BF00904772

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