Skip to main content
SpringerLink
Log in

Some reactions of hexafluoroacetone

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reactions are described of hexafluoroacetone with a number of compounds: hydroxylamine, hydrazoic acid, diazodiphenylmethane, some organomagnesium compounds, N-methylated anilines, N,P,P,P-tetraphenylphosphine imine, and ethyl hydrogen benzamidomalonate.

  2. 2.

    The strongly marked electrophilic reactivity of hexafluoroacetone was confirmed.

  3. 3.

    Some reactions of compounds prepared from hexafluoroacetone are described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. T. Morse, P. B. Ayscough, and L. C. Leitcn, Canad. J. Chem.33, 453 (1955).

    Google Scholar 

  2. N. Fukuhara and L. A. Bigelow, J. Amer. Chem. Soc.63, 783 (1941).

    Google Scholar 

  3. R. N. Haszeldine, J. Chem. Soc., 1954, 1273.

  4. R. N. Haszeldine, J. Chem. Soc., 1953, 3565.

  5. R. N. Haszeldine, Nature167, 139 (1951).

    Google Scholar 

  6. H. E. Simmons and D. W. Wiley, J. Amer. Chem. Soc.82, 2288 (1960).

    Google Scholar 

  7. I. L. Knunyants, Ch'en Ch'ing-yun and N. P. Gambaryan, Izv. AN SSSR. Otd. khim. n. 1960, 686.

  8. I. L. Knunyants, E. M. Rokhlin, N. P. Gambaryan, Yu. A. Cheburkov, and Ch'en Ch'ing-yun, Khim. nauka i prom.4, 802 (1959).

    Google Scholar 

  9. I. L. Knunyants, Ch'en Ch'ing-yun, and N. P. Gambaryan, Zh. VKhO im. Mendeleeva5, 112 (1960).

    Google Scholar 

  10. E. M. Rokhlin, N. P. Gambaryan, Ch'en Ch'ing-yun, and I. L. Knunyants, Dokl. AN SSSR134, 1367 (1960).

    Google Scholar 

  11. I. L. Knunyants and Yu. A. Cheburkov, Izv. AN SSSR. Otd. khim. n. 1960, 678.

  12. V. F. Plakhova and N. P. Gambaryan, Izv. AN SSSR. Otd. khim. n. 1962, 681.

  13. H. Zaugg, Inorganic Reactions [Russian translation], Collection8, IL, M., 1956, p. 569.

    Google Scholar 

  14. I. L. Knunyants, Ch'en Ch'ing-yun, N. P. Gambaryan and E. M. Rokhlin, Zh. VKhO im. Mendeleeva4, 114 (1960).

    Google Scholar 

  15. H. Wolff, in Organic Reactions [Russian translation], Collection 3, IL, M., 1951, p. 293.

    Google Scholar 

  16. D. C. England, J. Amer. Chem. Soc.,83, 2204 (1961).

    Google Scholar 

  17. E. T. McBee, J. F. Higgins, and O. R. Pierce, J. Amer. Chem. Soc.,74, 1387 (1952).

    Google Scholar 

  18. I. L. Knunyants and M. P. Krasuskaya, avt. svid. SSSR [Authors' Certificate] No. 138604; July 21, 1960.

  19. I. N. Nazarov and I. V. Torgov, Zh. obshch. khimii18, 1332 (1948).

    Google Scholar 

  20. H. Staudinger and E. Hauser, Helv. chim. acta4, 874(1921).

    Google Scholar 

  21. The Chemistry of Penicillin, N. Y., 1949, p. 775.

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    I. I. Knunyants, N. P. Gambaryan, Ch'en Ch'ing-yun & E. M. Rokhlin

Authors
  1. I. I. Knunyants
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. P. Gambaryan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ch'en Ch'ing-yun
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. M. Rokhlin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Knunyants, I.I., Gambaryan, N.P., Ch'ing-yun, C. et al. Some reactions of hexafluoroacetone. Russ Chem Bull 11, 633–640 (1962). https://doi.org/10.1007/BF00904766

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00904766

Keywords

Search

Navigation