Abstract
Polarographic investigations have been carried out on perchlorates of Tl(I), Zn(II), Cd(II), Mn(II), Co(II), Ni(II) and of bisbiphenylchromium(I)-iodide and ferrocene in anhydrous benzoyl fluoride (0,1m-tetrabutylammonium perchlorate). The half-wave potentials determined at 25 °C vs. the aqueous saturated calomel electrode are referred to the bisbiphenyl-chromium(I)-iodide-scale. The nature of the reduction at the electrode is described.
Zusammenfassung
Das polarographische Verhalten der Perchlorate von Tl(I), Zn(II), Cd(II), Mn(II), Co(II), Ni(II) sowie des Bisbiphenylchrom(I)-jodids und des Ferrocens wurde in wasserfreiem Benzoylfluorid (0,1m-Tetrabutylammoniumperchlorat) untersucht. Die bei 25 °C gegen die gesätt. wäßr. Kalomelelektrode gemessenen Halbwellenpotentiale wurden auf die Bisbiphenylchrom(I)-jodid-Skala bezogen. Die Art der Abscheidung an der Elektrode wird beschrieben.
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Gutmann, V., Cechak, H. Polarographische Untersuchungen in Benzoylfluorid. Monatshefte für Chemie 103, 1447–1452 (1972). https://doi.org/10.1007/BF00904529
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DOI: https://doi.org/10.1007/BF00904529