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Über das koordinationschemische Verhalten von Pyridin-2,6-di-thiocarbomethylamid

The chelating behaviour of pyridine-2.6-di-thiocarbomethylamide

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Copper, nickel and iron chelates of pyridine-2.6-di-thiocarbomethylamide were prepared. The discussion about the constitution of the obtained complex compounds is based on magnetic, spectroscopic, thermogravimetric and conductometric studies. 6-Methyl-2-thiocarbomethylamide reacts with copper(II) to give a copper(I) chelate.

Zusammenfassung

Die Komplexbildung von Pyridin-2,6-di-thiocarbomethylamid mit Kupfer-, Nickel- und Eisensalzen wird beschrieben. Die Konstitution der erhaltenen Komplexverbindungen wird an Hand magnetischer, spektroskopischer sowie thermogravimetrischer und konduktometrischer Untersuchungen diskutiert. 6-Methyl-2-thiocarbomethylamid reagient mit Kupfer(II) unter Bildung von Kupfer(I)-Komplexen.

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Literatur

  1. R. G. Pearson, J. Amer. Chem. Soc.85, 3533 (1963).

    Google Scholar 

  2. A. Spasson, E. Golovinsky undK. J. Markov, C. r. Acad. Sci. de Bulgarie13, 87 (1960);H. Celibonova-Lorer, S. Pančeva-Golovinska undE. Golovinsky, C. r. Acad. Sci. de Bulgarie16, 49 (1963);E. Golovinsky undS. Pančeva-Golovinska, Arzneimittelforsch.18, 1232 (1968).

    Google Scholar 

  3. K. I. Markov, Naturwissensch.47, 450 (1960);K. I. Markov undE. V. Golovinsky, C. r. Acad. Sci. de Bulgarie13, 199 (1960).

    Google Scholar 

  4. G. A. Heath undL. R. Stewart, Austral. J. Chem.22, 83 (1969);K. Knauer, P. Hemmerich undJ. W. D. van Voorst, Angew. Chem.79, 273 (1967);A. Röder undE. Bayer, Angew. Chem.79, 274 (1967).

    Google Scholar 

  5. H. O. Desseyn undM. A. Herman, Spectrochim. Acta23 A, 2457 (1967);H. O. Desseyn, W. A. Jacob undH. A. Herman, Spectrochim. Acta25 A, 1685 (1968).

    Google Scholar 

  6. W. Walter undH. P. Kubersky, Spectrochim. Acta26 A, 1155 (1970).

    Google Scholar 

  7. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds. Wiley. 1970;H. Siebert, Anwendungen der Schwingungsspektroskopie in der anorg. Chemie. Berlin-Heidelberg-New York: Springer. 1966.

  8. I. Yoe, A. Jones, Ind. Engng. Chem. Anal. Ed.16, 111 (1944).

    Google Scholar 

  9. I. A. McCleverty, Progr. Inorg. Chem.10, 49 (1968), Interscience, New York:E. Hoyer, W. Dietzsch, H. Hennig undW. Schroth, Chem. Ber.102, 603 (1969).

    Google Scholar 

  10. R. N. Sylva undH. A. Goodvin, Austral. J. Chem.21, 1081 (1968).

    Google Scholar 

  11. E. Bayer, Angew. Chem.76, 76 (1964).

    Google Scholar 

  12. R. W. Kluiber, Inorg. Chem.4, 829 (1965).

    Google Scholar 

  13. B. N. Figgis undJ. Lewis, Technique of Inorg. Chemistry, Vol. IV, p. 137, Interscience, New York 1965.

    Google Scholar 

  14. B. Emmert undM. Groll, Chem. Ber.86, 205, 208 (1953).

    Google Scholar 

  15. R. Wegler, E. Kühle undW. Schäfer, Angew. Chem.70, 351 (1958).

    Google Scholar 

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie der Universität Graz, Graz, Österreich

    E. Gagliardi & A. Popitsch

Authors
  1. E. Gagliardi
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  2. A. Popitsch
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Herrn Prof. Dr.Otto Kratky zum 70. Geburtstag gewidmet.

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Gagliardi, E., Popitsch, A. Über das koordinationschemische Verhalten von Pyridin-2,6-di-thiocarbomethylamid. Monatshefte für Chemie 103, 1337–1348 (1972). https://doi.org/10.1007/BF00904517

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  • DOI: https://doi.org/10.1007/BF00904517

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