Skip to main content
SpringerLink
Log in

Zur Umlagerung des Naphthalin-Molekülions vor der Bruchstückbildung

Rearrangement of the naphthalene molecular ion prior to fragmentation

  • Organische Chemie und Biochemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

By13C labelling studies it has been shown that the C atoms of the molecular ion of naphthalene in an energy range between IP and 18.8 eV have lost their identity (complete scrambling) prior to the loss of C2H2 in the source.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Massenspektroskopische Fragmentierungsreaktionen XV. XIV. Mitt. siehe:E. Flaskamp undH. Budzikiewicz, Biomed. Mass Spectrom., im Druck.

  2. T. W. Bentley undR. A. W. Johnstone, Adv. Phys. Org. Chem.8, 151 (1970).

    Google Scholar 

  3. C. G. McDonald undJ. S. Shannon, Austral. J. Chem.15, 771 (1962).

    Google Scholar 

  4. K. R. Jennings, Z. Naturforsch.A22, 454 (1967).

    Google Scholar 

  5. I. Horman, A. N. H. Yeo undD. H. Williams, J. Amer. Chem. Soc.92, 2131 (1970).

    Google Scholar 

  6. W. O. Perry, J. H. Beynon, W. E. Baitinger, J. W. Amy, R. M. Caprioli, R. N. Renaud, L. C. Leitch undS. Meyerson, J. Amer. Chem. Soc.92, 7236 (1970).

    Google Scholar 

  7. J. W. Beynon, R. M. Caprioli, W. O. Perry undW. E. Baitinger, J. Amer. Chem. Soc.94, 6828 (1972).

    Google Scholar 

  8. H. Budzikiewicz undR. Pesch, Org. Mass Spectrom.11, 821 (1976).

    Google Scholar 

  9. R. E. Winters, J. H. Collins undW. L. Courchene, J. Chem. Phys.45, 1931 (1966).

    Google Scholar 

  10. DiplomarbeitR. Stolze, Universität Köln, 1976.

  11. R. J. Van Brunt undM. E. Wacks, J. Chem. Phys.41, 3195 (1964).

    Google Scholar 

  12. J. H. D. Eland, P. J. Shepherd undC. J. Danby, Z. Naturforsch.A21, 1580 (1966).

    Google Scholar 

  13. F. Weygand undH. Simon, in:Houben-Weyl, Methoden der organischen Chemie,4/2, S. 643. Stuttgart. 1955.

  14. Autorenkollektiv, Organikum. Berlin. 1972.

  15. R. F. Nystrom undW. G. Brown, J. Amer. Chem. Soc.69, 2548 (1947).

    Google Scholar 

  16. L. Li undW. H. Elliott, J. Amer. Chem. Soc.74, 4089 (1952).

    Google Scholar 

  17. A. Roedig, in:Houben-Weyl, Methoden der organischen Chemie,5/4, S. 389. Stuttgart. 1960.

  18. E. L. Martin undL. F. Fieser, in:A. H. Blatt, Org. Synthesis, Coll. Vol.2, S. 569. New York-London. 1948.

  19. E. L. Martin, in:R. Adams, Org. Reactions,1, S. 155. New York-London. 1947.

  20. E. A. Braude, A. G. Brook undR. P. Linstead, J. Chem. Soc.1954, 3569.

  21. W. Hahn undR. Stroh, in:Houben-Weyl, Methoden der organischen Chemie,5/3, S. 899. Stuttgart. 1962.

  22. R. C. Huston undA. H. Agett, J. Org. Chem.6, 123 (1941).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Organische Chemie, Universität Köln, Greinstraße 4, D-5000, Köln 41, Bundesrepublik Deutschland

    Herbert Budzikiewicz & Rainer Stolze

Authors
  1. Herbert Budzikiewicz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rainer Stolze
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Budzikiewicz, H., Stolze, R. Zur Umlagerung des Naphthalin-Molekülions vor der Bruchstückbildung. Monatshefte für Chemie 108, 869–875 (1977). https://doi.org/10.1007/BF00898051

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00898051

Search

Navigation