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Structural dependence of the fragmentation of naphthalenesulfonyl halide and naphthalenesulfonamide molecules under electron ionization

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Abstract

By mass spectrometry it is found that naphthalene, 1-naphthalenesulfonyl chloride, 2-naphthalenesulfonyl fluoride, 2-naphthalenesulfonyl chloride, 1,5-naphthalenedisulfonyl chloride, 1-naphthalenesulfonamide, and 2-naphthalenesulfonamide evaporate congruently on heating and their saturated vapor is presented by the corresponding monomeric molecular forms. The relationship is established between the character of the fragmentation of molecules during electron ionization and the specific features of their geometric and electronic structures.

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Authors and Affiliations

  1. Ivanovo State University, Ivanovo, Russia

    N. I. Giricheva & G. V. Girichev

  2. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    V. M. Petrov

Authors
  1. N. I. Giricheva
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  2. G. V. Girichev
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  3. V. M. Petrov
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Correspondence to N. I. Giricheva.

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Original Russian Text © 2016 N. I. Giricheva, G. V. Girichev, V. M. Petrov.

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Giricheva, N.I., Girichev, G.V. & Petrov, V.M. Structural dependence of the fragmentation of naphthalenesulfonyl halide and naphthalenesulfonamide molecules under electron ionization. J Struct Chem 57, 97–103 (2016). https://doi.org/10.1134/S002247661601011X

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  • DOI: https://doi.org/10.1134/S002247661601011X

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